The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

Home

Cross Sections

Quantum Yields

Errata

Contact, Imprint, Acknowledgements

When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Alkenes,polyenes+radicals / Alkene radicals / CH2=CHCH2 / DeSain(2006)_298K_404nm

DATAFILE: CH2=CHCH2_DeSain(2006)_298K_404nm.txt
NAME: allyl radical
FORMULA: CH2=CHCH2
AUTHOR(YEAR): DeSain(2006)
T: 298K
λ: 404nm
BIBLIOGRAPHY: J.D. DeSain, L.E. Jusinski, and C.A. Taatjes, "Ultraviolet photochemistry of trichlorovinylsilane and allyltrichlorosilane: vinyl radical (HCCH2) and allyl radical (H2CCHCH2) production in 193 nm photolysis", Phys. Chem. Chem. Phys. 8, 2240-2248 (2006); DOI: 10.1039/B600755D
COMMENTS: The allyl radical was formed from the 193-nm photolsis of allyltrichlorosilane CH2=CHCH2SiCl3

The absorption cross section was derived by comparison of the transient visible absorption of the allyl radical with the 1315-nm iodine atom absorption resulting from the photolysis of vinyl iodide at 266 nm

Search cross sections

Species search:
Identifier search:
Reference search:
Full text search:
Recent additions:
since ago